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Internal convection within the liquid masses also plays in favour of freezing in the case of hot water, since being greater it favours the transfer of heat to the outside (inside the freezer)
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J Clin Oncol 26(15):2489-96, 2008
It is important to mention here that polyphenols cannot cross the blood-brain barrier and may have low bioavailability in the brain, but the intestinal lumen contains them in abundance, and hence, have the ability to modulate the microbiota, which is of utmost importance in the pathogenesis of ASD [197]
