nac vs acetyl glutathione Existing and potential therapeutic uses for N-acetylcysteine: The need for conversion to intracellular for antioxidant benefits π₯ NAC vs Glutathione: Comparing
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The reactivity and diverse functions of Cys are mirrored by a spectrum of susceptibilities and dysfunctions of their respective proteins, resulting in central roles for the Cys proteome in development, signal transduction, biologic defenses, aging, and disease [4,5,10]

We have chosen these antioxidants because of their ability to act as chemical reductants (glutathione, ascorbate, N-acetylcysteine, melatonin, tocopherol, thiamine, flavins, and chitosan), their similar chemistry and activation of endogenous antioxidant systems (proline, GABA, allantoin, and benzothiadiazole), and the frequency of reported exogenous application

however, from a chemical structure standpoint, hydrogen peroxide is not a free radical
