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The catalytic O 2 disproportionation by the material is based on the mechanism of outer-sphere proton-coupled one-electron transfer (the conversion between hydroxo-aquaMn(III) and monoaquaMn(II)), while the catalytic H 2 O 2 disproportionation involves inner-sphere proton-coupled two-electron transfer (the conversion between hydroxo-aquaMn(III) and oxo-hydroxoMn(V))

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[DOI] [PubMed] [Google Scholar] 88.Kim S.Y., Jeong E., Joung S.M., Lee J.Y